The Science of Candy: Sugar Chemistry - Chemical Safety Facts (2024)

The first step in making most candy is to dissolve sugar2(candy’s primary ingredient) into boiling water to form a syrup. The way the syrup is cooled determines whether the candy will becrystallineornon-crystalline.3

Crystalline Candy

Crystalline candy usually has fine sugar crystals and a lower sugar concentration than non-crystalline candy. To make crystalline candy, the sugary syrup is stirred continuously as it cools to ensure the sugar crystals remain small. Fudge is an example of a crystalline candy.

Non-Crystalline Candy

Non-crystalline candy is usually hard and brittle and has a higher sugar concentration than crystalline candy. Typically, non-crystalline candy is made by allowing the sugar syrup to cool over several days. Rock candy, lollipops and glass candy are some examples of non-crystalline candy.

Fun facts: Glass candy was historically used for stunts that involved people breaking windows. Gummies are made in a similar way to glass candy, but with gelatin added to the sugar syrup to give it a rubbery consistency.

The Science of Candy: Sugar Chemistry - Chemical Safety Facts (1)The Science of Fudge: How Fudge Is Made

Fudge is made by heating sugar and water to a temperature above the boiling point for water, which is 212° Fahrenheit.3The candy maker pours the syrup into a pan so it can cool faster. This technique helps prevent sucrose molecules from forming into a large crystal. Once cooled to 122° F, the syrup is stirred and scraped, forming many crystals at once. Continued stirring helps the sugar molecules spread among and bind to the crystal seeds. This helps keep the crystals small and creates the fudge’s milky texture.

More Common Candy Ingredients

Many candies also havepreservativesand other ingredients to keep them sweet and edible. The University of Hawaii’sFood Safety and Technologynewsletter article,Common Food Additives in Candy,4identifies several candy additives:

  • Butylated hydroxyanisole (BHA)is an antioxidant that prevents fats and oils from becoming rancid in candies such as peanut-butter cups.
  • Gum baseis one of the main ingredients in chewing gum. It’s made by blending and heating several vegetable or synthetic fibers with a softener such as paraffin and antioxidants.
  • Potassium sorbateis a preservative that is the potassium salt of sorbic acid,5which is also a preservative.

Caffeine6,ascorbic acidandcitric acidare also common candy ingredients. Citric acid gives candies like lemon drops their tart flavor.

For more information about candy and its chemistry, see these resources:

The Science of Candy: Sugar Chemistry - Chemical Safety Facts (2024)

FAQs

What is the chemistry of sugar in candy making? ›

In general, candy is made by dissolving sugar into water to create a solution. Granulated sugar, the most common type used in candy-making, is sucrose, a disaccharide molecule made up of glucose and fructose. When you force these two molecules to break apart, a very tasty reaction occurs: caramelization.

What is the chemical formula for candy? ›

Did you know that most types of candy are made of sugar from two kinds of plants: sugar cane and beets? The common form of sugar is called sucrose (C12H22O11), a molecule made up from glucose and fructose (see front cover).

Is making candy a chemical reaction? ›

When making glass candy, gummies, or marshmallows, the syrup is cooled down so quickly that no crystals can form at all. Making candies is actually chemistry in action. You manipulate the size of sugar crystals—even if you cannot see them—to produce an array of textures.

When making hard candy, the ingredients are heated to a boil then to 300. Of what is the purpose in heating the candy to this extreme? ›

Hard candy (like a lollypop or a Jolly Rancher) is made from sugar, corn syrup, water and flavoring. You heat the ingredients together and boil the mixture to drive off all of the water. Then you let the temperature rise. What you are left with is a pure sugar syrup at about 300 degrees.

What chemicals create sugar? ›

What is sugar? The white stuff we know as sugar is sucrose, a molecule composed of 12 atoms of carbon, 22 atoms of hydrogen, and 11 atoms of oxygen (C12H22O11). Like all compounds made from these three elements, sugar is a carbohydrate.

What chemicals react with sugar? ›

The sulfuric acid removes water from the sugar in a highly exothermic reaction, releasing heat, steam, and sulfur oxide fumes. Aside from the sulfurous odor, the reaction smells a lot like caramel. The white sugar turns into a black carbonized tube that pushes itself out of the beaker.

Is candy an acid or base? ›

Sour candies aren't the only types of edibles that register low on the pH scale. Did you know that most food measures a bit more acidic than alkaline? That's why your candies—even the sugary sweet candies and the rich chocolate ones—all should have ended up with a pH number below 7.

What acid is used in candy? ›

Citric acid is used in most confectionery as a 50% solution, but with hard candies, the powdered acid is usually used.

What chemical is in candy? ›

hydroxyanisole, some invertase, some glycerol monostearate . . . . Although some candy ingredients may have scary names, there is nothing ghoulish about them. Many of these ingredients play a significant role in making candy taste and look so good.

What is the role of sugar in candy? ›

In other confectionery products sugar contributes to texture and structure of traditional products. In high boil sweets (candies) sugar contributes to the boiling point elevation allowing a mixture to be boiled at higher temperatures.

What kind of sugar is used in candy? ›

Corn Syrup: Solid sugars aren't the only sweeteners used in candy making. Liquid sweeteners like corn syrup are incredibly common for making hard candies since using corn syrup creates a smooth texture. Invert Sugar: If you're making candy in bulk, consider using invert sugar, a sugar made primarily of sucrose.

What makes candy dissolve? ›

The candy coating is made up of coloring and sugar. The coloring and the sugar molecules both have positive and negative charges on them. The water molecule has positive and negative charges so it can attract and dissolve the color and sugar pretty well.

How long to boil fudge to soft ball stage? ›

How long does it take to make fudge:
  1. about 18 min to reach boiling.
  2. about 40 minutes to reach soft ball stage.
  3. 60 minutes to cool.
  4. 28 minutes to beat in a KitchenAid (your time for this may vary)
  5. 4 hours to set.

How does the weather impact candy making? ›

When I've made the candy on a warmer, humid day, it tends to be a stickier brittle. This is because the brittle takes longer to cool, and it reaches a point where it is no longer evaporating moisture into the air. It reabsorbs moisture from the air and forms unwanted crystals.

What is the science behind candy? ›

The secret behind candy making lies in the skill of manipulating the inherent size and shape of a sugar crystal — more formally known as sucrose. As the compound is heated to different temperatures, it will move through several candy stages until the desired effect is achieved.

What is the sugar in candy making? ›

Sugar stages
StageTemperatureSugar concentration
hard ball (e.g., nougat)121 to 130 °C (250 to 266 °F)90%
soft crack (e.g., salt water taffy)132 to 143 °C (270 to 289 °F)95%
hard crack (e.g., toffee)146 to 154 °C (295 to 309 °F)99%
clear liquid160 °C (320 °F)100%
5 more rows

What is the composition of candy sugar? ›

100% sugar (or nearly so), such as hard candies or creams. 95% sugar or more, with up to 5% other ingredients, such as marshmallows or nougats, and. 75 to 95% sugar, with 5 to 25% other ingredients, such as fudge or caramels.

What makes sugar sweet chemically? ›

The researchers found that fructose, glucose and mannose each formed hydrogen bonds of different lengths: sweeter-tasting sugars formed tighter, stronger bonds. The strength of the molecules' hydrogen bonds may be the primary factor in determining a sugar's level of sweetness, the authors suggest.

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